COMPOSITION OF CARBOHYDRATES IN FRESH WHEY AS WASTE IN TOFU PROCESSING
Apstrakt
Desizing of cotton fabric is a vital step in textile wet processing, directly influencing subsequent treatment and overall fabric performance. This study evaluates the effectiveness of hydrochloric acid, ammonium persulfate, and thermostable amylase asdesizing methods.. The performance of each method was assessed through key parameters: change in fabric mass, water penetration time, water absorption capacity, breaking strength, elongation at break, and air permeability. The results indicate distinct differences in the action mechanisms and effects of the desizing agents. Hydrochloric acid and ammonium persulfate demonstrated rapid sizing material removal, but also caused a noticeable reduction in mechanical properties and air permeability, which is attributed to their oxidative and acidic properties. In contrast, enzymatic desizing using thermostable amylase ensured effective removal of size material while maintaining fabric strength, elongation, and permeability characteristics. These findings support the potential of enzymatic desizing as a more fabric-friendly and sustainable alternative to conventional chemical methods, particularly for plain weave cotton substrates.
Acknowledgment
This research was supported by the Academy of Applied Studies Southern Serbia, Department of Technology and Art Studies Leskovac.
References
- Karmakar SR. Chemical Technology in the Pre-Treatment Processes of Textiles. Elsevier Science, Amsterdam, 1999.
- Choudhury AKR. Textile Preparation and Dyeing. Science Publishers, Enfield, USA, 2006.
- Zhang X, Baek N, Xu J, Yuan J, Fan X. Differences in the desizability of starches and the mechanism of inhibiting desizing. Textile Research Journal, 2022, 92(23-24), 4789-4798. https://dx.doi.org/doi:10.1177/00405175221110110
- Sarkodie B, Feng Q, Xu C, Xu Z. Desizability and Biodegradability of Textile Warp Sizing Materials and Their Mechanism: A Review. Journal of Polymers and the Environment, 2023, 31, 3317–3337. https://doi.org/10.1007/s10924-023-02801-5
- Ul-Haq N, Nasir H. Cleaner production technologies in desizing of cotton fabric. The Journal of the Textile Institute, 2011, 103(3), 304–310. https://doi.org/10.1080/00405000.2011.570045
- Singh S, Hooda S. Effect of pretreatment on physical properties of cotton fabric. International Journal of Ecology and Environmental Sciences, 2021, 3, 472-476.
- Var C, Palamutcu S. Sustainable Approaches in Textile-Sizing Process. In: Sustainable Manufacturing Practices in the Textiles and Fashion Sector. Springer Nature Switzerland, 2024, 55-74. https://doi.org/10.1007/978-3-031-51362-6_3
- Jeffrey DF, John FR. Modification of starch granules by hydrolysis with hydrochloric acid in various alcohols, and the formation of new kinds of limit dextrins. Carbohydrate Research, 1992, 227, 163-170. https://doi.org/10.1016/0008-6215(92)85068-B
- Yuya N, Isao K, Masaru G, Yoshiko N, Naoyoshi I. The Formation of Resistant Starch during Acid Hydrolysis of High-amylose Corn Starch. Journal of Applied Glycoscience, 2013, 60(2), 123-130. https://doi.org/10.5458/jag.jag.JAG2012_008
- Yu H, Fang Q, Cao Y, Liu Z. Effect of HCl on starch structure and properties of starch-based wood adhesives. BioResources, 2016, 11(1), 1721-1728.
- Xuerong F, Qiang W, Li C, Ping W. Hydrolysis of modified starches with amylases used for textile desizing. Journal of Biotechnology, 2008, 136, S384-S385. https://doi.org/10.1016/j.jbiotec.2008.07.885
- Inventor KA, Inventor GR. Liquid oxidative desizing agent and process for oxidative deszing. United States Patent, Patent Number: 4,478,737, 1984.
- Evonik Persulfates Technical Information Brochure. Accessed Jun 2023.
- Grujić D, Savić A, Papuga S, Miloševic M, Kolar M, Milanovic PM, Milanovic JZ. Optimization of enzymatic desizing and scouring of cotton fabric by response surface methodology. Cellulose Chemistry and Technology, 2023, 57(1-2), 167-184. https://doi.org/10.35812/CelluloseChemTechnol.2023.57.17
- Landage SM. 3 – Biotechnological approaches in desizing of textile materials, In: The Textile Institute Book Series, Applications of Biotechnology for Sustainable Textile Production. Editor(s): O.L. Shanmugasundaram, Woodhead Publishing, 2022, 47-73. https://doi.org/10.1016/B978-0-323-85651-5.00012-8
- Rehman A, Saeed A, Asad W, Khan I, Hayat A, Rehman MU, Shah TA, Sitotaw B, Dawoud TM, Bourhia M. Eco-friendly textile desizing with indigenously produced amylase from Bacillus cereus AS2. Scientific Reports, 2023, 13, 11991, 1-12. https://doi.org/10.1038/s41598-023-38956-3